自由基聚合

RAFT调控的活性自由基聚合动力学研究及其在合成复杂结构聚合物上的应用

Kinetics of RAFT Based Living Free Radical Polymerization and Application in Synthesis of Complex Architecture Polymer

结果表明铜离子介入的MMA在BSA上的接枝聚合属于自由基聚合反应，并表现出乳液聚合的特征。

The results reveal that copper mediated graft copolymerization of MMA on BSA is free radical polymerization , similar to an emulsion polymerization .

Fe（Ⅲ）体系催化的丙烯酰胺反向原子转移自由基聚合

Reverse atom transfer radical polymerization of arylamine catalyzed by iron (ⅲ) system

N，N-二甲氨基甲基丙烯酸乙酯的原子转移自由基聚合

Study on the atom transfer radical polymerization of n , n - ( dimethylamino ) ethyl methacrylate

原子转移自由基聚合合成具有pH敏感性壳聚糖材料及其对辅酶A的控制释放

Preparation of pH-sensitive chitosan by atom transfer radical polymerization and its controlled delivery on coenzyme A

具有RAFT链转移过程的活性自由基聚合的MonteCarlo模拟

Monte Carlo Simulation on Living Radical Polymerization with RAFT Process

通过活性／可控自由基聚合合成了支链结构可控的SBS－g－PMMA接枝共聚物。

The SBS-g-PMMA with well-controlled branch chain was synthesized through living / controlled radical polymerization .

基于RAFT过程的丙烯酸可控自由基聚合

Controlled Radical Homopolymerization of Acrylic Acid Based on RAFT Polymerization

St和MMA在不同反应介质中的RAFT活性自由基聚合

RAFT Living Free Radical Polymerization of St and MMA in Different Reaction Media

基于RAFT过程的MMA可控自由基聚合及嵌段共聚物的合成

Controlled Radical Homopolymerization and Block Copolymerization of Methyl Methacrylate Based on RAFT Process

增溶剂存在下苯乙烯细乳液RAFT活性自由基聚合

Reversible Addition-Fragmentation Transfer ( RAFT ) Living Polymerization of Styrene Miniemulsion in the Presence of Solubilizer

ESR研究结果表明，MMA单体聚合遵循自由基聚合机理。

The ESR results show that the polymerization of MMA follows a free radical mechanism .

基于活性自由基聚合的纳米SiO2表面接枝及其应用

Grafting Polymers from the Surface of Silica Nanoparticles via Living Radical Polymerization and Their Applications

此预聚物再与苯乙烯（ST）通过自由基聚合，得到交联的嵌段共聚物。

The vinyl-terminated prepolymer polymerized with styrene ( ST ) in the presence of free radical initiator to obtain a crosslinked block copolymer .

负载卤化镍（NiX2/HD）催化MMA的原子转移自由基聚合

Atom Transfer Radical Polymerization of MMA Catalyzed by Hybrid Supported Nickel Catalyst

通过RAFT自由基聚合合成含叠氮端基的聚N-异丙基丙烯酰胺氮氧自由基&过渡金属配合物的结构和磁性研究

Synthesis of Azido-capped Poly ( N-isopropylacrylamide ) by RAFT Free Radical Polymerization Structures and Magnetic Research of Nitroxide Radicals-Transition Metal Coordination Complexes

p-苯乙烯磺酸钠（SS）水溶液辐射引发自由基聚合在γ-环糊精（CD）存在下被加速。

Polymerization of sodium p - styrenesulfonate ( SS ) in aqueous solution was accelerated in the presence of γ - cyclodextrin (γ - CD ) .

此外，RAFT聚合还可用于各种自由基聚合的模式：溶液，乳浊液和悬浮聚合。

In addition , RAFT polymerization can also be used for a variety of radical polymerization mode : solution , emulsion and suspension polymerization .

可逆加成-断链链转移（RAFT）聚合是活性自由基聚合方法之一，它结合了活性聚合和自由基聚合的优点。

Reversible Addition-Fragmentation chain Transfer polymerization is one of the living radical polymerizations . It combines the advantage of living polymerization and radical polymerization .

本论文采用原子转移自由基聚合制备了Poly（MethylMethacrylate）-g-polystyrene接枝共聚物和四臂星型聚苯乙烯。

In this dissertation , poly ( methyl methacrylate-co-hydroxyethyl methacrylate ) - g-polystyrene graft copolymer and star-shaped polystyrene with four arms were prepared by atom transfer radical polymerization .

本研究选用马来酸酐为单体，以过氧化物为引发剂，通过自由基聚合的方式合成制备聚马来酸（PMA）水溶液。

The PMA solution was prepared by free radical polymerization with maleic anhydride acting as monomer in presence of peroxide .

利用合成的二硫代苯甲酸苯乙基酯为链转移剂，成功实现了MMA和St在本体及甲苯中的RAFT活性自由基聚合，结果表明均有较为明显的活性聚合特征。

The rarefied was used as transfer agent for the RAFT polymerization of MMA and St in bulk and toluene , the polymerizations were found with living characters .

以丙烯酰胺为原料，通过自由基聚合和高分子化学反应合成了降粘剂A-1。

The viscosity reducer A-1 was synthesized from acrylic amide by radical polymerization and high molecular reaction .

原子转移自由基聚合（ATRP）在星形聚合物合成中的应用

Progress of Atom Transfer Radical Polymerization ( ATRP ) Applied to the Synthesis of Star Polymers

用SiO2交联剂（SiO2HPA）交联甲基丙烯酸甲酯（MMA）自由基聚合制备PMMASiO2纳米复合材料。

Polymethylmethacrylate ( PMMA ) / silica nanocomposites were prepared by conventional radical polymerization of methlymethacrylate ( MMA ) in the presence of silica crosslinking agent ( SiO_2-HPA ) .

聚乙烯吡咯烷酮（PVP）是N-乙烯基吡咯烷酮（NVP）经自由基聚合而成的一类高分子精细化学品。

Poly vinyl pyrrolidone ( PVP ) is polymeric fine chemical obtained by free radical polymerization of N vinyl pyrrolidone ( NVP ) .

原子转移自由基聚合（ATRP）技术是合成结构规整性聚合物的有效途径。

Atom transfer radical polymerization ( ATRP ) is an effective route to synthesize polymers with well-defined structures .

原子转移自由基聚合（ATRP）方法是一种新发展起来的可控/活性自由基聚合方法，在合成结构可控共聚物过程中具有广泛应用。

Atom transfer radical polymerization ( ATRP ) is a new effective method to prepare controlled block copolymers .

综述了近10年来采用原子转移自由基聚合（ATRP）法合成星形聚合物的研究进展。

Star polymers synthesized by atom transfer radical polymerization ( ATRP ) in recent ten years are reviewed .

以二硫代羧酸酯和三硫代碳酸酯为链转移剂的可逆加成裂解链转移（RAFT）自由基聚合的发现，在活性自由基聚合领域是一个重要突破。

RAFT uses the dithiocarbamate or trithiocarbonate derivatives as transfer agents , the polymerization has excellent living behavior , which is an important breakthrough in the development of living free-radical polymerization .