种子乳液聚合

RAFT种子乳液聚合反应初期的MonteCarlo模拟

Monte Carlo Simulations for the Very Beginning of RAFT Seeded Emulsion Polymerization

采用种子乳液聚合工艺合成纯丙乳液，并以其为成膜物质配制低VOC乳胶涂料。

Acrylate emulsion was synthesized by seeded emulsion polymerization , and it was taken as film forming matter to prepare latex coating with low VOC .

种子乳液聚合制备可发气P（St/BVA）-PSt核壳微球

Preparation of foamable P ( St / BVA ) - PSt core-shell microparticles by seeding emulsion polymerization

AC对St或MMA为壳层单体种子乳液聚合的影响

Effect of AC on seeding emulsion polymerization using St or MMA as shell monomer

用种子乳液聚合法合成的ASA复合胶乳粒子的形态

Morphology of ASA Composite Latex Particles Synthesized by Seeded Emulsion Polymerization

种子乳液聚合法制备纳米SiO2/苯丙复合乳液

Preparation of nano-SiO_2 / styrene-acrylic emulsion by seed emulsion polymerization

成功地使用了种子乳液聚合方法制备出粒径为300nm左右的苯乙烯（Styrene）/丙烯酸（acrylicacid）共聚小球。

Copolymer nanospheres of styrene / acrylic acid were prepared successfully by seeded emulsion polymerization .

烷基硫酸钠对MMA种子乳液聚合的影响

Study on the Effect of Sodium Alkyl Sulfate on Seed Emulsion Polymerization of MMA

采用适时补皂、种子乳液聚合方法合成粒径大、分布窄的SBR胶乳。

The SBR latex with large particle diameter and narrow distribution were synthesized by reinforcing additional emulsifier and seeding emulsion co-polymerization .

采用种子乳液聚合技术，以K2S2O8为引发剂合成了一系列PBgSAN接枝共聚物。

A series of PB g SAN copolymers were synthesized by seed emulsion polymerization using K 2S 2O 8 as the initiator .

采用种子乳液聚合手段，合成了具有核壳结构的抗冲击改性剂ACR。

A kind of impact modifier ACR with core - shell structure was synthesized by emulsion polymerization .

本文以种子乳液聚合的方法合成了聚硅氧烷接枝聚丙烯酸酯微乳液，用红外光谱（IR）进行结构表征，用电子显微镜（TEM）测定乳液的粒径。

Graft copolymer micro-emulsion of polyacrylate and polysiloxane had been prepared through seeded emulsion polymerization , its structure was characterized by IR . The particle size was determined through TEM photographing .

采用种子乳液聚合法制备出了聚丙烯酸丁酯/聚甲基丙烯酸甲酯（PBA/PMMA）核壳型聚合物粒子，并对其表观形貌及结构进行了SEM和FTIR分析。

Polybutylacrylate / polymethylmethacrylate ( PBA / PMMA ) core-shell polymer particles are prepared through seed emulsion polymerization . SEM and FTIR analyses are also conducted to their appearance and structure .

采用种子乳液聚合法进行PBA胶乳粒径放大方法简便、效果明显。

The results showed that this method was a good way for preparing PBA latex with large particle size .

采用自制的丙烯酸酯化聚氨酯（APU）和种子乳液聚合的方法，制备了一种P（APU-BA）/PMMA型的核壳粒子。

P ( APU-BA ) / PMMA core-shell particles were prepared by polymerization of self-made acrylate polyurethane ( APU ) and seed emulsion .

采用种子乳液聚合技术在聚丁二烯（PB）乳胶粒上接枝共聚苯乙烯（St）和丙烯腈（AN），合成了一系列PB-g-SAN共聚物（ABS）。

A series of PB-g-SAN copolymer ( ABS ) were synthesized by grafting styrene and acrylonitrile onto polybutadiene ( PB ) latex rubber particles with seeded emulsion polymerization technique .

采用无皂种子乳液聚合制备了具有微空腔形态的聚（甲基丙烯酸甲酯共甲基丙烯酸）／聚苯乙烯〔P（MMA－MAA）／PS〕复合微粒并讨论了形态形成原理。

Poly ( methyl methacrylate - co-methacrylic acid ) / polystyrene ( P ( MMA - MAA ) / PS ) composite particles with microvoid morphology were prepared by soap-free seeded emulsion polymerization .

探讨了种子乳液聚合的过程，分析了包覆机理，讨论了SiO2的用量对聚合反应速率及残渣率的影响。

The process of in suit emulsion polymerization was approached , its encapsulation mechanics was analyzed , and the effect of SiO 2 amount on the reacting velocity and sediment percentage was discussed .

通过种子乳液聚合，合成了PB-g-SAN接枝共聚物，与SAN树脂共混后制得了ABS树脂。

A series of PB-g-SAN ( polybutadiene-grafting-styrene and acrylonitrile ) grafting copolymer was synthesized by seeds-emulsion polymerization , and then blended with SAN ( styrene-acrylonitrile copolymer ) resin to prepare ABS resin .

采用种子乳液聚合法合成了丁苯橡胶接枝聚甲基丙烯酸乙酯共聚物（SBR－g－PEMA）。

Poly ( butadiene styrene ) / poly ( ethyl methacrylate ) graft copolymers ( SBR g PEMA ) were synthesized by seeded emulsion polymerization and blended with high impact polystyrene ( HIPS ) .

介绍了种子乳液聚合法、原位乳液聚合法和溶液聚合转相法三种典型的制备PUA复合乳液的工艺及其最新进展。

Three typical preparation processes and their current development of PUA hybrid emulsion , seeded emulsion polymerization , emulsion polymerization in situ and phase-inversion solution polymerization , are reviewed .

结果表明，通过辐射引发PSI种子乳液聚合，制得了具有核壳式结构的P（SI-BA-MMA）共聚乳胶粒子。

The latex film properties were also studied . The results show that the P ( SI-BA-MMA ) composite latex has core-shell structure with PSI as the core and polyacrylate as the shell .

综述了聚氨酯-聚丙烯酸酯复合乳液（PUA）的制备方法，包括共混交联法、种子乳液聚合法、互穿聚合物网络聚合法、乳液共聚合法等。

Preparation methods of compound emulsion of polyurethane-polyacrylate ( PUA ) are reviewed . It includes co-mixture crosslinking , seeded emulsion polymerization , interpenetrating polymer network polymerization and copolymerization emulsion .

种子乳液聚合制备MCPU-PMMA复合乳液

Synthesis of MCPU-PMMA hybrid emulsion through seeded emulsion polymerization

用含碘化合物作为链转移剂，通过种子乳液聚合的方法合成PCP-b-PS两嵌段聚合物。

Taking iodide as chain-transfer agent , PCP-b-PS diblock copolymers were prepared through seed emulsion polymerization .

系统研究了乳化剂、交联剂、引发剂等因素对PBA乳液聚合反应及胶乳性质的影响，发现可以用种子乳液聚合方法成功控制橡胶粒子的直径。

The influences of emulsifier level , crosslinking agent level , initiator level had been studied systematically . It was found that the rubber particle size can be controlled by using the seed emulsion polymerization technique .

用种子乳液聚合法，以OP-10作为乳化剂，以K2S2O8作为引发剂，以丙烯酸（AA）为单体接枝改性石蜡（PF）乳液，合成了石蜡丙烯酸（PFAA）复合乳液。

With nonionic OP-10 as emulsifier , potassium persulfate ( K_2S_2O_8 ) as initiator , acrylic acid ( AA ) modified paraffine ( PF ) hybrid emulsion was synthesized by seed emulsion polymerization .

本论文先采用种子乳液聚合方法合成核壳乳液，再通过碱溶胀法，制备出粒径为900nm左右的中空乳胶粒。

In this thesis , hollow latex particles having an average diameter of 900 nm were prepared by seeded emulsion polymerization followed by alkali swelling .

通过种子乳液聚合法制备了具有核-壳结构的CaCO3/PBA/PMMA和CaCO3/PBA/P（MMA-St）复合粒子，并分别将其与PVC共混制备复合材料。

In the case of PMMA / CaCO_3 composite particle as fillers , the impact strength of PVC-matrix composites can increase to 24.52 kJ / m ~ 2.CaCO_3/PBA/PMMA and CaCO_3 / PBA / P ( MMA-St ) composite particles were prepared by seeded emulsion polymerization .

经傅里叶变换红外光谱测定证明，在种子乳液聚合阶段，PVA-SH与MMA单体发生了接枝反应，形成具有PVA-S-PMMA结构的线型两亲接枝聚合物。

Online Fourier transform infrared spectroscopy ( FT-IR ) monitoring test indicated that graft reaction of PVA-SH and MMA was taken place mainly at the seed emulsion polymerizing stage forming a linear PVA-S-PMMA structure graft polymer .