负离子聚合

丁二烯负离子聚合溶剂极性经验参数与反应参数间的关系

Relationships between solvent polarity empirical parameter and reactivity parameters in butadiene anionic polymerization

醇钾和酚钾助引发剂在负离子聚合中的应用研究进展

Advance in application of potassium alkoxides and potassium phenoxides as promoter in anionic polymerization

考察了以1，1，4，4－四苯基－1，4－二锂丁烷（TPB－DiLi）为引发剂，二哌啶乙烷（DPE）为结构调节剂，环己烷为溶剂的丁二烯负离子聚合。

The anionic polymerization of butadiene was obtained with 1,1,4,4-tetraphenyl-1,4-dilithium butane as initiator , dipiperidinoethane ( DPE ) as modifier and cyclohexane as solvent .

异戊二烯在环己烷-二氧六环中的负离子聚合机理

Mechanism of anionic polymerization of isoprene in cyclohexane - dioxane

异戊二烯-环己烷-乙醚体系负离子聚合产物的微观结构

Microstructure of product obtained from anionic polymerization of isoprene using Et2O as polar additive

异戊二烯/THF负离子聚合产物的微观结构

Microstructure of product obtained from anionic polymerization of isoprene using THF as polar additive

负离子聚合法合成端羟羧基液体聚丁二烯橡胶的研究

Preparation and structure of hydroxyl carboxyl - terminated liquid polybutadiene rubber by anionic polymerization

（甲基）丙烯酸烷基酯的负离子聚合Ⅰ.聚合特点及适用的单官能团引发剂体系

Anionic polymerization of alkyl ( meth ) acrylates ⅰ . Polymerization characteristics and suitable mono-functional initiator systems

推导了异戊二烯在环已烷-二氧六环混合溶剂中的负离子聚合机理，并通过实验进行了验证。

The mechanism of anionic polymerization of isoprene with cyclohexane and dioxane as solvent was studied and improved by experiment .

研究表明，丁二烯聚合机理原则上同样适用于异戊二烯的负离子聚合。

The experimental results showed that the mechanism of anionic polymerization of butadiene was also fit for the anionic polymerization of isoprene .

分别研究了两种溶剂（环己烷和抽余油）对氧的吸附和脱附作用；氧对正丁基锂的反应历程以及对由正丁基锂引发的丁二烯负离子聚合过程的影响。

The effects of two kinds of solvents , cyclohexane and extracted oil , on the adsorption and desorption of oxygen , and oxygen on reaction mechanism of n-butyl lithium and on anionic polymerization of butadiene with n-butyl lithium as initiator were studied respectively .

多级连续搅拌反应器中丁二烯-苯乙烯负离子溶液聚合动力学

Kinetics of anionic solution polymerization of butadiene - styrene in continuous stirring - tank reactors