相转移催化

相转移催化（PTC）反应研究&Ⅲ.1-~（14）C，1,1-二溴-2-苯基环丙烷及其取代物的合成

Studies of Phase Transfer Catalysis & ⅲ . Preparation of 1 - ~ ( 14 ) C-1.1-Dibromo-2-Phenyl-cyclopropane and Its Derivatives

以Mn（Ⅲ）/Mn（Ⅱ）为间接氧化还原体系，用间接电氧化的方法，在相转移催化条件下对醇类的氧化进行了研究。

Indirect electrooxidation of alcohols was studied by using Mn (ⅲ) / Mn (ⅱ) as a redox system under phase transfer catalysis .

相转移催化2－甲基吲哚的N－烷基化反应

Studies of Phase Transfer Catalysis for N-Alkylation of 2-Methylindole

相转移催化合成3-（N，N-二烯丙基）氨基-4-甲氧基乙酰苯胺

Synthesis of 3 - ( N , N-Diallyl ) Amino-4-Methoxy Acetanilide by phase-Transfer catalysis

四乙基碘化铵相转移催化合成N，N&二乙基苯胺

Study of Phase Transfer Catalytic Synthesis of N , N-Diethylaniline with Tetraethyl Ammonium Iodide

2－甲基吲哚－N－烷基化相转移催化机理及其动力学研究

Studies of Mechanism and Kinetics of N-Alkylation of 2-Methyl Indole Using Phase Transfer Catalyst

相转移催化合成N，N′-二（3,5-二甲基吡唑）烷

Phase Transfer Catalytical Synthesis of N , N ' - Bis ( 3,5-dimethylpyrazolyl ) alkanes

PEG对樟脑酰亚胺N-烃基化反应的相转移催化效果

The phase-transfer catalytic effect of PEG in the N-alkylation of camphorimide

2,2′联吡啶在水/硝基苯界面对Co（Ⅱ）的相转移催化

The phase transfer of co (ⅱ) catalyzed by 2,2 ′ - bipyridine at the water / nitrobenzene interface

相转移催化氧化脱除FCC汽油中含硫化合物的研究

FCC Gasoline Desulfurization by Phase Transfer Catalyzed Oxidation

以KF&Al2O3为固碱相转移催化合成环丙烷羧酸酯

Synthesis of Cyclopropane Carboxylates through Phase Transfer Catalysis with Potassium Fluoride Coated Alumina as A Solid Base

固-液相转移催化合成Ⅴ.醛亚胺的Michael加成和羰基加成反应合成α-氨基酸

Solid-Liquid Phase Transfer Catalytic Synthesis ⅴ . Michael Addition , Carbonyl Addition Reactions of Aldimines for the Synthesis of α - Amino Acids

相转移催化反应的研究IV.聚乙二醇催化机理

Studies on Phase Transfer Catalysis IV. Catalytic Mechanism of Polyethylene Glycol

方法以1,3,5三甲苯为起始原料，经过两步溴化、氰化、甲基化和N烷基化5步反应合成阿那曲唑，在第二步和最后一步反应中使用相转移催化方法。

Method 1,3,5-trimethylbenzene was selected as the start material . The final product was obtained in five steps , including two steps bromination , cyanidation , methylation and N - alkylation .

以氯霉素生产中的副产物邻硝基乙苯为原料，经铁酸还原和相转移催化N－烷基化反应合成了N，N－二丁基邻乙基苯胺（DBEA）。

N , N dibutyl o ethyl aniline ( DBEA ) was synthesized with o nitro ethyl benzene by reduction and alkylation .

固液相转移催化N-烷基化反应Azone的合成

Solid-liquid phase transfer catalytic N-alkylation & synthesis of azone

阴离子相转移催化的Friedel-Crafts烷基化反应

The Friedel-Crafts Alkylation by Anion Phase Transfer Catalysis

相转移催化合成BLP

Synthesis of BLP with Phase Transfer Catalysis

Wittig反应的研究（Ⅷ）&相转移催化二苯基烯丙基型Wittig反应

STUDIES ON THE WITTIG REACTION (ⅶ) & Phase Transfer Catalyzed Wittig Reaction of Allyl Diphenyl Ylids

通过钠盐制备、相转移催化、水洗分离、精馏四段工艺得到GA的总收率为78.2%，纯度为97.0%。

℃ . A total GA yield of 78.2 % and purity 97.0 % were obtained from the entire process including SA preparation , phase transfer reaction , water washing and distillation .

方法采用相转移催化法合成了6个喜树碱糖苷衍生物（7~12），经1HNMR，IR和MS分析确证了化合物的结构。

Methods Six camptothecin glycosides ( 7-12 ) were synthesized by phase transfer catalysis . The structures of all compounds synthesized were determined by ~ ( 1 ) H NMR , IR and MS.

考察了RuO4相转移催化氧化法合成对硝基苯甲酸的各种影响因素。

Various factors affecting the preparation of p-nitrobenzoic acid by PTC-RuO_4-NaClO method were investigated .

最好的方法是用氯乙醇和8羟基喹啉在K2CO3/PEC600/THF条件下进行相转移催化反应。

The phase transfer catalytic reaction of chloroethanol with 8-hydroxyquinoline under the condition of K_2CO_3 / PEG-600 / THF is the most suitable method .

相转移催化法合成酸性红玉3GS

Synthesis of Acid Rubine 3GS With Phase Transfer Catalysis

聚乙二醇相转移催化作用下Darzens酯缩合异硫氰基乙酸乙酯的合成

Polyethylene Glycols Used as Phase Transfer Catalyst for Darzens Glycidic Ester Condensation

其中N4溴丁基邻苯二甲酰亚胺（1）改用相转移催化法合成，收率由文献的65%提高到88%。

N ( 4 bromobutyl ) phthalimide was prepared by a phase transfer catalyst in 88 % yield .

相转移催化合成紫外线吸收剂UV-326

Synthesis of ultraviolet absorbent UV-326 by phase transfer catalysis

相转移催化下有机硼烷的反应&由KBH4和烯烃一锅反应合成二烷基酮

PTC Reaction of Organoborane : A One-pot Synthesis of Ketone via KBH_4 and Alkene

采用聚乙二醇相转移催化合成甲基异柳磷，讨论了反应物配比、催化剂用量、溶液pH值、温度、时间对反应的影响，试验得出反应的最佳工艺条件，其收率由80%提高到86.7%。

Catalytic synthesis of isofenphos-methyl with polyethylene glycol , the ratio of raw material , pH of solvent , reaction temperature and reaction time were discussed , and then optimum technological condition were obtained , the yield of product increased from 80 % to 86.7 % .

Galvinoxyl/K3Fe（CN）6/KOH复合体系相转移催化合成对称取代偶氮苯

Oxidation of Aromatic Amines to Symmetrical Substituted Azobenzenes under Phase - Transfer Catalysis with Galvinoxyl / K_3Fe ( CN ) _6 / KOH System