环己烯

环己烯在超临界CO2介质中的催化氧化

Catalytic Oxidation of Cyclohexene in Supercritical CO 2

对反应的主要影响因素进行了考察，如反应时间、温度，环己烯与H2O2物料配比，催化剂种类及用量，助催化剂种类及用量，溶剂种类及用量等。

The key factors influencing the epoxidation were also studied , such as reaction time , temperature , mole ratio between cyclohexene and H2O2 , the kinds and amount of catalysts , of cocatalyst , and those of solvent .

C（60）与环己烷及环己烯离子体系的气相反应

Gas-Phase Reactions of C_ ( 60 ) with the Ion Systems of Cyclohexane and Cyclohexene

环己烯催化氧化制己二酸的HPLC法研究

HPLC for Catalytic Oxidation Product of Cyclohexene

MnSalophen/Al2O3高压催化环己烯合成环己烯酮

Oxidation of Cyclohexene to Cyclohexenone on MnSalophen / Al_2O_3 Catalyst under High Pressure

另外发现少量Zn的加入有利于提高Ru-Zn-B/Al2O3-ZrO2催化剂的环己烯选择性。

Ru catalyst containing a small amount of zinc is in favor of improving selectivity of cyclohexene .

本文采用我国有着充足供应的过氧化氢（H2O2）为氧化剂，开展环己烯绿色氧化合成己二酸的研究。

In this work , H_2O_2 with ample supply in China was used as oxidant in the synthesis of adipic acid from cyclohexene .

通过对天然手性源（R）-香芹酮的10步常规转化以24%的总产率完成了环己烯酮的合成。

The cyclohexenone was obtained by several functional transformation of ( R ) - ( - ) - carvone in 10 steps and 24 % overall yield .

环己烯分子2b和3a轨道的电子动量谱学研究

Electron Momentum Spectroscopy Investigation on the 2b and 3a Orbitals of Cyclohexene

Co~（2+）固载PVA促进传递膜渗透汽化分离环己烯/环己烷的研究

Study on Fixed - site Carrier PVA Membrane Containing Co ~ 2 + for Pervaporation Separation of Cyclohexane / Cyclohexene

以环己烯作裂解原料，制备出新型的覆炭载体CCA。在温度一定的情况下，γ-Al2O3上覆炭量与时间呈线性关系。

CCA carrier was prepared by cyclohexene cracked to carbon compound over the r - Al2O3 under higher temperature 400C-650C .

Ce（Ⅳ）Y吸附剂的强B酸中心均引起噻吩和环己烯吸附方式的变化，生成相应的质子化产物，对甲苯的吸附方式无影响。

The strong Bronsted acid sites of Ce ( IV ) Y lead to the protonation of thiophene and CHE , but have no effect on the adsorption mode of toluene .

SalenAl（OPr）催化CO2和氧化环己烯共聚反应

Salenal ( opr ) catalyst for the copolymerization of co_2 and cyclohexene oxide

Pd（OAc）2／HQ／FePc催化环己烯氧化合成环己酮反应机理

Mechanism of Oxidation of Cyclohexene to Cyclohexanone Catalyzed by Pd ( OAc ) _2 / HO / FePc

[Co（p-Me-PPA）2，（H2O）2]Cl的合成及其催化环己烯氧化反应的研究

Study on Synthesis of complex [ co ( p-me-ppa ) _2 ( h_2o ) _2 ] cl and catalytic oxidation of Cyclohexene

纳米固体超强酸SO4~（2-）/ZrO2-La2O3催化合成环己烯研究

Study on the Solid Superacid SO_4 ~ ( 2 - ) / ZrO_2-La_2O_3 Catalyzed Synthesis of Cyclohexene

同时对于Ru催化剂而言，通常需要添加助剂来抑制活性和提高环己烯的选择性。

Meanwhile , for the Ru catalyst , it is generally needed to add promoter to lower its catalytic activity and improve the selectivity to cyclohexene .

用绿色氧化剂H2O2进行环己烯的环氧化反应，其还原产物为水，无有毒、无有害物质，不会给环境带来新的污染，为绿色合成过程；

The green oxidant H2O2 is used in this work with the reductive production of H2O . So there is no baneful materials to release and it can be ascribed to a kind of green progresss .

FePc结构对Pd（OAc）2/HQ/FePc催化环己烯氧化活性的影响

Effect of FePc Structure on the Activity in the Oxidation of Cyclohexene Catalyzed by Pd ( OAc ) _2 / HQ / FePc

SnCl4催化合成环己烯

Synthesis of cyclohexene catalyzed by SnCl_4

用GC-MS和GC-IR研究环己烯分子氧氧化的络合催化反应

GC MS and GC IR in Studies on Catalytic Oxidation of Cyclohexene in the Presence of Molecular Oxygen

苯加氢制环己烯为结构敏感反应，Ru微晶粒径应控制在10nm以内；

The reaction of benzene selective hydrogenation to cyclohexene is sensitive to structure , so the Ru crystallite size should be controlled within 10nm ;

Zn-Co双金属氰化络合物催化氧化环己烯/二氧化碳共聚反应

Copolymerization of Cyclohexene Oxide with Carbon Dioxide Catalyzed by Zn-Co Double Metal Cyanide Complex

提出了由环己烯制备1,2-环己二醇的工艺路线，考察了物料配比，反应温度，反应时间，加料方式，PH值等诸多因素的影响。

The method of synthesizing trans-1,2-cyclohexanediol was investigated . The effecting factors on synthesizing 1,2-cyclohexanediol , such as raw material ratio , reaction temperature , reaction time , method of adding raw materials , pH value , and so on , were discussed .

通过GC-MS分析发现，酮类转化为相应的烷基取代醇，酚类中甲氧基含量相对较高，有少量环己烯生成。

By GC-MS analysis it is observed that ketones were transformed into the corresponding alkyl alcohol , methoxyl content was relatively high in the phenolic , and a small amount of cyclohexene is formed .

通过300MHz1HNMR，75MHz13CNMR，IR与MS分析法对该化合物进行了结构分析，确认这一化合物为4（1甲基乙烯基）1环己烯1乙醇。

The compound was identified that it was 4 ( 1 methylethenyl ) 1 cyclohexenyl 1 ethanol with the structure analysed by 300 MHz 1 HNMR 、 75 MHz 13 CNMR 、 IR and MS.

将筛选出的催化剂用于催化H2O2氧化环己烯合成己二酸的反应，探讨了反应时间、反应温度、H2O2与环己烯摩尔比、催化剂加入量等对反应的影响。

The filtering catalysts was used in synthesis of adipic acid reaction . The key factors influencing the oxidation were also studied , such as reaction time , reaction temperature , mole ratio between H_2O_2 and cyclohexene , the amount of catalysts .

乙酰辅酶A羧化酶（ACCase）是除草剂的作用靶标之一，此类除草剂主要有两类：芳氧苯氧丙酸类（APP）和环己烯酮类（环己二酮，环己烯二酮，CHD）。

Acetyl-CoA Carboxylase is one of targets acted by herbicides . There are mainly two types of ACCase : aryloxyphenoxypropionates ( AOPP , APP ) and cyclohexanediones ( CHD ) .

本文主要内容为苯选择加氢制环己烯Ru-Zn催化剂的制备与表征。

The preparation and characterization of Ru-Zn catalysts for benzene selective hydrogenation to cyclohexene were studied in this paper .

在改性Y沸石上邻二甲苯异构化和歧化反应同时进行，SY沸石的歧化反应变化规律与环己烯氢转移反应相似。

O-xylene isomerization is accompanied by disproportionation reaction on modified Y zeolites . For SY zeolites the results of the o-xylene disproportionation reaction are consistent with that of the cyclohexene hydrogen transfer reaction .