热力学参数

pH法测定若干金属离子与天门冬酰胺络合反应的热力学参数

The determination of thermodynamic parameters associated with the formation of some metal-asparagine complexes

用BENDER状态方程计算N2ArO2体系的热力学参数

Application of Bender state equation in Calculating thermodynamic parameters of N_2-Ar-O_2 system

湿位涡、热力学参数CD与涡度、散度演化

The Effects of Moist Potential Vorticity and Thermodynamic Parameter C_D on Evolution of Vorticity and Divergence

NITi合金热循环相变过程热力学参数研究

Thermodynamics Study of Transformation in Process of Thermal Cycling in Ni-Ti Alloy

首次采用微量热仪，测定了DNA在土壤胶体和矿物表面吸附的热力学参数，为DNA在土壤活性颗粒表面吸附机理的阐明提供了新证据。

To our knowledge , this is the first paper providing the thermodynamic data of DNA adsorption on soil colloids and minerals .

气液色谱法研究一些Lewis酸碱加合反应的热力学参数

Study on the Thermodynamic Parameters for Adducts of Lewis A-B by Gas Liquid Chromatography

热力学参数表明，改性玉米秸秆对Cr（Ⅵ）的吸附是一个自发吸热过程，升高温度有利于吸附的进行。

The thermodynamic parameters showed that the adsorption of Cr ( VI ) onto MCS was an spontaneous and endothermic process .

本论文采用电化学方法，结合光谱方法，主要研究了二萘嵌苯类化合物的性质，及此类化合物与G-四链体DNA之间的相互作用，获得结合模式、结合常数等热力学参数。

In this paper , several electrochemical methods were used to study the interactions between G-quadruplexes DNA and derivations of perylene , and binding constants were obtained .

用~1HNMR测定吡啶和2,6-二甲基吡啶的pKα和热力学参数

Determination of pk_ α values and thermodynamic parameter of pyridine and 2 , 6-Lutidine by ~ 1h NMR

糖炭／硅胶复合吸附剂对Cr（Ⅵ）的吸附行为符合Langmuir吸附等温方程，并计算了相关模型参数和吸附热力学参数。

Equilibrium data fit to Langmuir adsorption isotherm and the relative parameters of Langmuir adsorption isotherm and adsorption thermodynamics are calculated .

用荧光光谱法对该量子点与HSA之间的相互作用进行了研究，通过实验测定的结合常数、基本的热力学参数确定了量子点与HSA的键合模式及作用机理。

The interaction between the as-prepared QDs and HSA was studied by fluorescence technique .

热力学参数说明NCP与BSA间的主要作用力为疏水作用力。

From the thermodynamic parameters , we concluded that the action force was mainly hydrophobic interaction .

给出了该蛋白质在H2O、甲醇和乙二醇水溶液中变性的热力学参数值。

The thermodynamic parameters of denaturation of the proteins in water , methanol and ethylene glycol solution were obtained .

使用Gilbert解吸装置测定了分散染料上染二醋纤的热力学参数。

Gilbert adsorbing apparatus has been used to measure thermodynamic parameters with disperse dyes on secondary cellulose acetate .

根据σ～SDS浓度曲线，求得SDS／NaCl体系的临界胶束浓度，借助质量作用模型得出对应条件下的胶束化热力学参数。

Critical micellar concentration of SDS / NaCl is obtained from surface tension curve . Then thermodynamic parameters of corresponding microscopic aggregation are obtained using Mass-Action Model .

结果表明：随直链淀粉含量的增加，淀粉的RVA糊化参数和DSC热力学参数有很大差异。

The results showed that there was great difference of the RVA pasting parameter and DSC thermal properties with the increase of amylose content .

根据热力学参数状态图所确定的条件，热压合成了AlON陶瓷。

AlON ceramics was synthesized by hot_press sintering under the conditions given by phase stability diagram .

含RDX的低燃速丁羟推进剂配方，采用最小自由能法进行理论计算，研究了RDX和改性草酸铵对热力学参数的影响。

The effects of dosage of RDX and modified ammonium oxalate ( CA ) on the thermodynamic parameters were studied by the minimum free energy method via theoretical calculation .

根据热力学参数确定马钱子碱与BSA之间的作用力类型主要为疏水性相互作用。

The process of binding was a spontaneous molecular interaction in which entropy increased and Gibbs free energy decreased , indicating that the interaction between brucine and BSA was driven mainly by hydrophobic force .

用分光光度滴定法在不同温度、不同pH值条件下测定了纤维素纤维接枝β-环糊精与苯二酚类分子形成超分子包合物的表观热力学参数。

The complex stability constants for the 1 ∶ 1 inclusion complexation of various dihydroxybenzenes ( pyrocatechol , hydroquinone , resorcinol ) with cellulose fibre grafted β - cyclodextrin have been determined by means of spectrophotometric titrations at different temperatures in aqueous solutions with different pH values .

计算了温度为2073K时Al-O-N系热力学参数状态图。

The phase stability diagrams of Al-O-N system at 2 073 K were calculated .

最后我们用ITC的方法，研究了其它类型季铵盐配体修饰的金纳米粒子，与BLGA/BLGB结合过程中热力学参数的变化。

Finally , ITC was applied to study the thermodynamic parameters for binding of BLGA / BLGB and gold nanoparticles modified by other quaternary ammonium ligands .

结果表明，用不同测量方法得到TIM的变性过程均高度协同，没有观察到折叠中间态，应用单分子二态去折叠模型计算了TIM去折叠的热力学参数。

Results show that the unfolding of TIM is highly cooperative and no folding intermediate was detected in the experimental conditions used . The thermodynamic parameters of TIM during guanidine denaturation were calculated according to a two-state unimolecular unfolding model .

通过热力学参数分析，结果表明该循环在自变量的选取、流程的优化、循环特性等方面都不同于常规的Rankine循环。

Through thermodynamic analysis of parameters , the results show that the selection of chief independent parameters , optimization of flow processes and cycle characteristics are different from an ordinary Rankine cycle .

Mg-Al，Sr-Al和Ba-Al熔体的作用浓度计算模型和热力学参数确定

Calculating models of mass action concentrations for Mg-Al , Sr-Al and Ba-Al melts and determination of their thermodynamic parameters

用Sekine方法处理实验数据，从而获得了ΔH0、ΔS0和ΔG0等一系列相关的热力学参数。

The experimental data were treated with Sekine method . Some thermodynamic parameters , such as Δ H0 ,Δ S0 and Δ G0 are obtained .

用扫描电镜和电子探针研究了Al共晶接触反应钎焊液相的润湿行为，以分步法观察Cu在Al表面的润湿铺展过程，并运用热力学参数分析Al共晶接触反应钎焊机理。

The wetting behavior of liquid phase for Al eutectic reaction brazing was studied using SEM and EDX . A step by step approach was used to observe the spreading of Cu on Al on eutectic condition . The mechanism of Al eutectic reaction brazing was analyzed using thermodynamical parameters .

威力（Weinig）集团提供实木加工所需的全套的生产线通过全线型分析方法求得速率常数及有关有热力学参数。

The rate constants and other thermodynamic parameters were obtained by complete line shape analysis .

方法：分别采用紫外吸收光谱法、相溶解度法研究了3种环糊精（CDs）在水溶液中对PGE1的包合作用、增溶作用及包合过程中热力学参数的变化。

Methods : The intermolecular reaction between the host and the guest agents , soluble effects of 3 CDs on PGE1 in aqueous solution and changes of thermodynamic profiles in the complexation were determined by UV absorption spectra and the phase solubility .

以Lineweaver-Burk双倒数方程和能量传递原理分别计算了三者与BSA反应的结合常数（KLB）和结合距离（r）以及由热力学参数的计算判断了三种小分子物质与BSA结合的作用力类型；

The binding constants KLB and distances r of these compounds and BSA were calculated respectively , according to Lineweaver-Burk equation and energy transfer theory . And every type of conjugation effort was estimated by the calculation of thermodynamic parameters .