无皂乳液聚合

无皂乳液聚合的稳定方法和应用进展

Stabilization Methods and Application of Emulsifier-free Emulsion Polymerization

高固含量稳定无皂乳液聚合的研究&MMA/BA/MAA（AA）无皂乳液聚合体系

A study on high solid content and stable emulsifier-free emulsion polymerization & mma / ba / maa ( aa ) emulsifier-free emulsion polymerization system

以P（BA/AANa）齐聚物为基础，合成了一种性能优越的无皂乳液聚合（SFEP）丙烯酸酯涂料。

A new soap free poly ( arcylate / methlacrylate ) emulsion is synthesized with P ( BA / AANa ) obligmer .

无皂乳液聚合法合成单分散交联PS纳米微球

Preparation of Monodisperse Cross-linked PS Nano microspheres by Emulsifier-free Emulsion Polymerization

苯乙烯-丙烯酸丁酯无皂乳液聚合动力学及TEM分析

The Kinetics of Emulsifier-Free Emulsion Polymerization of Styrene-Butyl Acrylate and TEM Analysis

原位无皂乳液聚合硅灰石接枝PMMA反应机理及表征

Reaction Mechanism and Characterization of In-situ Soap Free Emulsion Polymerization of Wollastonite-g-PMMA

无皂乳液聚合制备纳米SiO2/丙烯酸酯复合乳液

Structure and Properties of Nano-SiO_2 / Acrylic Composite Emulsion Prepared via Soap-Free Emulsion Polymerization

苯乙烯RAFT无皂乳液聚合体系的研究

Study on Emulsifier-free Emulsion Polymerization of Styrene Systems with Reversible Addition-Fragmentation Chain Transfer ( RAFT ) Process

阳离子型共聚单体DMC在MMA/BA/DMC无皂乳液聚合中的影响

Effect of Cationic Comonomer DMC on MMA / BA / DMC Soap-free Emulsion Polymerization

在微波辐照和丙酮存在下，进行了苯乙烯（ST）和甲基丙烯酸甲酯（MMA）的无皂乳液聚合。

Emulsifier free emulsion polymerization of styrene in acetone water medium has been carried out using microwave irradiation .

无皂乳液聚合法制备P（St-MMA-SPMAP）单分散乳胶颗粒

Preparation of mono-dispersed colloids of p ( st-mma-spmap ) by soap-free emulsion copolymerization

原位无皂乳液聚合制备纳米SiO2/聚丙烯酸酯杂化材料纸张表面增强剂的性能研究

The properties of SiO_2 / polyacrylate hybrid materials paper strength agent prepared by in-situ emulsifier-free emulsion polymerization

利用无皂乳液聚合的方法合成了表面含有羧基的亚微米级聚（苯乙烯-共-丙烯酸）（P（St-co-AA））微球。

Surface-carboxylic poly ( styrene-co-acrylic )( P ( St-co-AA )) sub-micron spheres were prepared by soap-free emulsion polymerization .

反应性乳化剂性质的不同，对MMA／BA无皂乳液聚合及乳液性能存在较大的影响。

There were many effects on MMA / BA emulsifier-free emulsion polymerization and its properties because of the difference of reactive surfactants .

以改性氧化锌微粒为种子进行无皂乳液聚合，引发剂引发St单体生成低聚分子链吸附缠绕在氧化锌微粒表面，最终形成ZnO/PSt包覆复合微粒。

With modified ZnO particles as seeds , soapless emulsion polymerization was carried out . The PSt oligomers were absorbed and trapped on the surface of ZnO particles .

利用TEM对几种乳化剂体系的乳液聚合进行比较后发现，在无皂乳液聚合体系中，乳胶粒的均匀性和粘连、形变等都得到了控制。

Using TEM to compare emulsion polymerization of several emulsifier system , we found that the homogeneity and adhesion and deformation of the particles of emulsion could be controlled .

离子单体对P（4VP-BA）/P（BA-St-SS-Na~+）核壳无皂乳液聚合的影响

Effect Of Ionic Monomer On P ( 4VP-BA ) / P ( BA-St-SS-Na ~ + ) Core-shell emulsifier-free emulsion

采用无皂乳液聚合法，我们制备了粒径500nm的聚苯乙烯（PS）微球。

Polystyrene ( PS ) spheres with a diameter of 500 nm were synthesized by emulsifier-free emulsion polymerization .

无皂乳液聚合法是在无乳化剂存在的环境中，利用纳米二氧化硅表面的吸附力，单体（MMA）在其表面进行聚合，包裹纳米二氧化硅表面，改善界面状况。

Soap-free polymerization method means monomers ( MMA ) polymerize around the surface of nano-silica without soup , absorbed by the force of surface .

该共聚物可以作为大分子引发剂再引发甲基丙烯酸甲酯（MMA）进行无皂乳液聚合。

The results showed that the surfactant-free polymerization of MMA can be carried out by using saponified AMS-MAn copolymer , without any other initiator and emulsifier .

以水性聚氨酯PU为种子，加入丙烯酸酯单体进行无皂乳液聚合，合成了聚氨酯/聚丙烯酸酯（PUA）复合乳液。

Polyurethane / Polyacrylate ( PUA ) hybrid latexes were prepared by seeded surfactant-free emulsion polymerization , the polyurethane aqueous dispersions were used as seed particles .

MMA-St无皂乳液聚合成核机理探讨

On nucleation mechanism in emulsifier-free emulsion copolymerization of methyl methacrylate and styrene

聚合工艺及m（MMA）/m（EA）对MMA-EA-AA三元无皂乳液聚合及乳胶粒性质的影响

Influences of Polymerization Technology and m ( MMA ) / m ( EA ) on the Soap-free Emulsion Polymerization of MMA-EA-AA and Their Latex Particle Properties

通过无皂乳液聚合，利用一步法和两步法分别制备了单分散的聚（苯乙烯-甲基丙烯酸甲酯-甲基丙烯酸丙基磺酸钾）（P（S-MMA-SPMAP））乳胶颗粒。

The mono-dispersed colloids of poly ( styrene-methyl methacrylate - 3-sulfopropyl methacrylate , potassium salt ) P ( S-MMA-SPMAP ) were prepared with soap-free emulsion copolymerization using one-step or two-step method .

AOPA用于高固含量稳定无皂乳液聚合的研究

A study on high solid content and stable emulsifier free emulsion polymerization that added with AOPA

甲醇存在下St-BA-HEA体系的无皂乳液聚合研究

Study on Soap-Free Emulsion Polymerization of System St-BA-HEA in the Presence of Methanol

合成了一系列的自交联封端型聚氨酯-丙烯酸酯（PUA）复合乳液。合成步骤主要分为三步：（1）运用无皂乳液聚合方法合成含羟基的PUA复合乳液；

A series of aqueous blocked self-crosslinking hybrid polyurethane-acrylate ( PUA ) emulsions has been synthesized in three steps : ( 1 ) synthesis of hydroxyl terminated PUA prepolymers by soap-free emulsion polymerization ;

在功能单体存在下进行无皂乳液聚合，制备抗菌聚合物微球，并用电镜表征其形貌、用XPS表征其表层物质的组成、用电镜和粒度分析仪表征其粒径大小及分布。

Prepared antimicrobial polymer microsphere by soap-free emulsion polymerization in the presence of functional monomer synthesized by 1 . And characterized their morphology by electron microscopy , characterized their shell composition by XPS , characterized their size and distribution by electron microscopy and particle size analysis instrument . 3 .

首先通过无皂乳液聚合反应合成了高交联的核壳型苯乙烯-二乙烯苯共聚物（PS-DVB）微球，用CCl4溶解未交联的PS核得到中空PS-DVB胶囊。

We synthesized the crosslinked core @ shell poly ( styrene-co-divinylbenzene ) spheres ( PS-DVB spheres ) by soap-free emulsion polymerization . The uncrosslinked PS core was removed via dissolution by CCl4 and hollow PS-DVB capsules were formed .

水性无皂乳液聚合是最新研究的热点，在涂料和粘胶剂市场有很大的发展前景。

Water-soluble surfactant-free Emulsion Polymerization is the newest hotspot of research .