振动量子数
- 网络vibrational quantum number
振动量子数-
标识了所有谱线的相对振动量子数和绝对转动量子数，并同时对多组数据进行了最小二乘法拟合，首次得到了精确的分子转动常数和平衡常数。
These lines were globally fitted using least-square fitting and assigned with relatively vibrational quantum numbers and absolute rotational quantum numbers . New rotational constants Bu , were used to derive equilibrium parameters for the first time .
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研究结果指出，前两个反应在H的初始振动基态时的反应阈能分别为20kcal·mol－1和65kcal·mol－1，反应阈能随振动量子数增大而减小。
It is shown that the threshold energy for the first and second reactions , at the vibrational ground state of H , are 20 kcal · mol-1 and 65 kcal · mol-1 , respectively .