樟脑磺酸

固相反应法制备樟脑磺酸掺杂聚苯胺

Solid-state Synthesis of Camphorsulfonic Acid Doped Polyaniline

HPLC测定樟脑磺酸钠注射液的含量

Determination of the Content of Sodium Camphor Sulfonate Injection by HPLC

以天然樟脑磺酸为起始原料，经过简单的三步反应合成了C2-对称的二樟脑磺酰胺配体9-11。

From commercially available starting materials natural camphor , C2-symmetric bis ( hydroxycamphorsulfonamide ) ligand 9-11 were prepared in three simple steps .

聚苯胺在有机溶剂中掺杂樟脑磺酸的UV-Vis光谱

On the UV Vis Spectra of Polyaniline Doped with Camphor Sulfonic Acid in Organic Solvent

采用再掺杂方法制得了樟脑磺酸掺杂的聚苯胺（PAn-CSA），用溶液共混法制备PAn／BR导电复合膜.研究了聚苯胺与顺丁橡胶（BR）复合膜在间甲酚二次掺杂前后电导率的变化。

PAn-CSA was prepared by means of doping method , and solution blend was applied to the preparation of PAn / BR conducive composite film . The difference in conductivity of composite film between secondary doping and after secondary doping was investigated .

主要研究内容及实验结果如下：（1）制备了一种新型的樟脑磺酸掺杂聚苯胺（PANI-（D-CSA））复合阳极。

Main results are as follows : ( 1 ) A novel polyaniline-camphorsulfonic acid ( PANI - ( D-CSA )) composite anode was prepared .

研究了用樟脑磺酸不同程度掺杂聚苯胺、同摩尔比例不同种类有机磺酸掺杂聚苯胺、I2掺杂MEH-PPV，对其红外反射性的影响；

The infrared reflective behavior of the polyanilines doped with different proportion of camphor sulphonic acid , and the polyanilines doped with different kinds of organic sulphonic acid in same mole , and MEH-PPV doped with li are researched .

形成的机理是：手性樟脑磺酸与苯胺通过N-H氢键作用，同时手性碳的诱导使苯胺能有序地在聚苯胺低聚物同一侧面结合而形成了螺旋结构。

The formation mechanism is that through interaction of N-H hydrogen bond between camphor sulfonic acid and aniline , aniline can orderly combine and form at the same side of the oligomer , due to the induction of chiral carbon .

界面扩散聚合法制备樟脑磺酸掺杂聚苯胺纳米管或纳米纤维及其电化学电容行为研究

Preparation and characterization of camphor sulfonic acid doped polyaniline nano-tubes and nano-fibrils by interfacial polymerization

通过调整樟脑磺酸掺杂量，膜的致密均匀性显著改善，电导率增加。

By adjusting the amount of dopant camphor sulfonic acid , the dense of membrane and uniformity was significantly improved with the increase of electrical conductivity .

樟脑磺酸掺杂的聚苯胺的热稳定性较好，热失重温度可达约280℃，有利于生产加工。

The thermal stability of Camphor sulfonic acid ( CSA ) doped polyaniline is better and the thermal gravity temperature of 280 ℃, is conducive to production and processing .

指出对于乳液或水溶液化学氧化聚合制得的聚苯胺，大分子功能质子酸如樟脑磺酸、十二烷基苯磺酸掺杂是其获得溶致液晶性的唯一途径。

It is pointed out that the only way to endow polyaniline prepared by chemical oxidization in emulsion or aqueous solution with LC properties is to dope polyaniline with functionalized protonic acids , such as camphor sulfonic acid or dodecylbenzene sulfonic acid .

DL-苯甘氨酸用d-樟脑磺酸作拆分试剂，乙酸作溶剂，在水杨醛催化下发生不对称转化反应，得到D-苯甘氨酸·d-樟脑磺酸盐（收率为85.90%，光学纯度为99.80%）。

The asymmetric transformation of DL-phenylglycine via formation of salt with d-camphor sulfonic acid was carried out by using salicylaldehyde as a catalyst for epimerization in acetic acid , giving D-phenylglycine d-camphor sulfonic salt ( 85.90 % yield , 99.80 % optical purity ) .

首先用盐酸西布曲明制备出实验用西布曲明，然后用D-樟脑-10-磺酸进行拆分。

The sibutramine was prepared from sibutramine hydrochloride , its resolution was proceeded using D-camphor-10-sulfonic acid .

d-樟脑-10-磺酸的合成工艺研究

Studies on Synthesis of d-Camphor-10-Sulfoacid

描述了带基片聚苯胺膜的光学性能测试结果，讨论了D-樟脑-10-磺酸的掺杂对聚苯胺红外反射性能的影响及其原理。

In this paper , The optical properties of polyaniline coating were determinated . The properties of infrared reflection of the polyaniline dopped with different proportion of D Camphor 10 sulphonic acid and the principle were reviewed .